A MO-Theoretical Treatment of Toluene-Formaldehyde Reaction Catalyzed by Solid Acids
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چکیده
منابع مشابه
Zeolite catalyzed alkylation of toluene by alcohol
Vapor-phase methylation of toluene using methanol and its isopropylation with 2-propanol has been investigated ina down flow reactor under atmospheric conditions using N2 carrier over a series of surface modified andunmodified ZSM-5 (Si/Al= 60-170) loaded with H3PO4, differing in the external surface treatment of the zeolites.The feed molar ratios of toluene/methanol and toluene/2-propanol were...
متن کاملzeolite catalyzed alkylation of toluene by alcohol
vapor-phase methylation of toluene using methanol and its isopropylation with 2-propanol has been investigated ina down flow reactor under atmospheric conditions using n2 carrier over a series of surface modified andunmodified zsm-5 (si/al= 60-170) loaded with h3po4, differing in the external surface treatment of the zeolites.the feed molar ratios of toluene/methanol and toluene/2-propanol were...
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A highly enantioselective Biginelli reaction promoted by chiral spirocyclic SPINOL-phosphoric acids has been developed. Under the optimized conditions with 5 mol% catalyst loading, a wide range of optically active dihydropyrimidinethiones (DHPMs) were obtained in high yields (up to 98%) with good to excellent enantioselectivities (up to 99% ee). The synthetic utility of this method was demonstr...
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ژورنال
عنوان ژورنال: Bulletin of The Japan Petroleum Institute
سال: 1971
ISSN: 0582-4656
DOI: 10.1627/jpi1959.13.182